Controlling through-space and through-bond intramolecular charge transfer in bridged D–D?–A TADF emitters
نویسندگان
چکیده
Donor–donor?–acceptor molecules where the donor? bridges donor and acceptor have different possible interaction pathways for charge transfer.
منابع مشابه
Controlling the Conformational Changes in Donor–Acceptor [4]-Dendralenes through Intramolecular Charge-Transfer Processes
The synthesis of two [4]-dendralene compounds incorporating thiophene-(p-nitrophenyl) donor-acceptor units is presented. The dendralenes adopt two different conformers in solution and solid state and the transformation between the structures can be controlled by light and heat. The electron-donating components of the dendralenes are represented by bromothienyl (in 13) and ethylenedioxythiophene...
متن کاملNew intramolecular through-space charge transfer emission: tunable dual fluorescence of terfluorenes.
We have synthesized a series of new terfluorene derivatives, and investigated their novel fluorescence emission behaviors. We have demonstrated a new intramolecular through-space charge transfer emission experimentally and theoretically. This is the first report on spiroconjugation-like caused fluorescence emission, which could be tuned by the electron nature of pendent groups without changing ...
متن کاملEnergy transfer pathways in dinuclear heteroleptic polypyridyl complexes: through-space vs through-bond interaction mechanisms.
A series of homo- and heteronuclear ruthenium and osmium polypyridyl complexes with the bridging ligands 1,3-bis(5-(2-pyridyl)-1H-1,2,4-triazol-3-yl)benzene (H(2)mL) and 1,4-bis(5-(2-pyridyl)-1H-1,2,4-triazol-3-yl)benzene (H(2)pL) are reported. The photophysical properties of these compounds are investigated, and particular attention is paid to the heteronuclear (RuOs) compounds, which exhibit ...
متن کاملChallenges in distinguishing superexchange and hopping mechanisms of intramolecular charge transfer through fluorene oligomers.
The temperature dependence of intramolecular charge separation in a series of donor-bridge-acceptor molecules having phenothiazine (PTZ) donors, 2,7-oligofluorene FL(n) (n = 1-4) bridges, and perylene-3,4:9,10-bis(dicarboximide) (PDI) acceptors was studied. Photoexcitation of PDI to its lowest excited singlet state results in oxidation of PTZ via the FL(n) bridge. In toluene, the temperature de...
متن کاملTunneling through weak interactions: comparison of through-space-, H-bond-, and through-bond-mediated tunneling.
Results from ab initio electronic structure theory calculations on model systems allow for the detailed comparison of tunneling through covalently bonded contacts, hydrogen bonds, and van der Waals contacts. Considerable geometrical sensitivity as well as an exponential distance dependence of the tunneling is observed for tunneling through various nonbonded contacts. However, the fundamental re...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Materials Chemistry C
سال: 2021
ISSN: ['2050-7526', '2050-7534']
DOI: https://doi.org/10.1039/d1tc02316k